A non-fused mono-meso-free pentaphyrin and its rhodium(I) complex.
نویسندگان
چکیده
5,10,15,20-Tetrakis(pentafluorophenyl) [22]pentaphyrin(1.1.1.1.1) 7 was synthesised and its bis-rhodium(I) complex 12 has been revealed to be a non-fused, yet planar pentaphyrin with an inverted pyrrole. Both 7 and 12 are aromatic, showing sharp Soret-like bands and diatropic ring currents.
منابع مشابه
Stepwise π-extension of meso-alkylidenyl porphyrins through sequential 1,3-dipolar cycloaddition and redox reactions.
Several regioselectively π-extended, pyrrole fused porphyrinoids have been synthesized by the 1,3-dipolar cycloaddition of meso-alkylidene-(benzi)porphyrins. Pd(II) complexes gave oxidation resistant, bis-pyrrole fused adducts. The repeated 1,3-dipolar cycloaddition followed by oxidation-reduction of pentaphyrin analogs afforded π-extended porphyrin analogs.
متن کاملSupporting Information Modification Effect of meso-Hexakis(pentafluorophenyl) [26]Hexaphyrin Aggregates on the Photocatalytic Water Splitting
Fig. S3 TEM images of (a) meso-tetrakis(pentafulorophenyl)porphyrin (compound 1), (b) N-fused pentaphyrin (compound 2), (c) meso-hexakis(pentafluorophenyl) [26] hexaphyrin (compound 3), (d) mesoheptakis(pentafluorophenyl) heptaphyrin (compound 4) (e) meso-octakis(pentafluorophenyl) octaphyrin (compound 5), and (f) meso-nonakis(pentafluorophenyl) nonaphyrin (compound 6) on IrO2-GaN:ZnO photocata...
متن کاملmeso-Alkylidene (m-benzi)pentaphyrin: a modified pentaphyrin bearing exocyclic double bonds at meso-positions.
meso-Alkylidene (m-benzi)pentaphyrin containing exocyclic C=C double bonds at two meso-positions is synthesized and fully characterized for the first time. The single crystal X-ray crystallographic analysis shows a concave conformation with two pyrrole rings inverted. The first protonation occurs exclusively at core nitrogen. The synthesized compound displays concentration dependent chromogenic...
متن کاملSynthesis and spectroscopic behaviour of metal complexes of meso-alkylidenyl carbaporphyrinoids and their expanded analogues.
Treatment of meso-malonylidene-(m-benzi)porphyrin and meso-malonylidene-(m-benzi)pentaphyrin with Pd(ii), Au(iii), Ni(ii) and Ag(i) afforded the corresponding metal complexes. The synthesized metal complexes were characterized by spectroscopy including single crystal X-ray, NMR and mass spectrometry. Most metal complexes were stable in solution. The metal complexes showed strong absorption in t...
متن کاملDesymmetrizations of meso-tert-norbornenols by rhodium(I)-catalyzed enantioselective retro-allylations.
Rhodium-catalyzed desymmetrizations of meso-tert-norbornenols by retro-allylations generate allyl-rhodium species that allow for a rich and diverse downstream reactivity.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 48 54 شماره
صفحات -
تاریخ انتشار 2012